Organosilicon compounds : experiment (physico-chemical studies) and applications /
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| Author / Creator: | Lee, Vladimir Ya., author. |
|---|---|
| Imprint: | Amsterdam : Academic Press, 2017. |
| Description: | 1 online resource. |
| Language: | English |
| Subject: | |
| Format: | E-Resource Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/11361786 |
Table of Contents:
- Front Cover; Organosilicon Compounds; Copyright Page; Contents; List of Contributors; About the Editor; Preface; I. Physico-Chemical Studies; 1 X-Ray Crystallography of Organosilicon Compounds (Electron Density and Chemical Bonding in Organosilicon Compounds); 1.1 Introduction; 1.1.1 Multipole Model; 1.1.2 Further Models; 1.1.3 Extracting Bonding Features From the EDD; 1.2 The Nature of the Si-X Bond; 1.3 Aromaticity in Silicon-Containing Compounds; 1.3.1 Three-Membered Rings; 1.3.2 Four-Membered Rings; 1.3.3 Five-Membered Rings; 1.3.4 Six-Membered Rings
- 1.4 Multiple Bonds and Low-Valent Silicon1.4.1 Multiple Bonds; 1.4.2 Silylenes; 1.4.3 Silaallenes and Silylones; 1.5 Conclusions; References; Further Reading; 2 29Si NMR Spectroscopy; Abbreviations; 2.1 General Aspects and Chemical Shifts; 2.2 Special Considerations; 2.2.1 Referencing of the 29Si NMR Chemical Shifts; 2.2.2 29Si NMR Pulse Techniques; 2.2.3 Coupling Constants; 2.3 Conclusions; References; 3 Thermochemistry of Organosilicon Compounds; Abbreviations; 3.1 Introduction; 3.2 Compounds of Tetravalent Silicon; 3.2.1 SiX4 Compounds; 3.2.2 SiXnY4−n Compounds; 3.2.2.1 Halides
- 3.2.2.2 Methylsilanes and methyl silicon halides3.2.3 Organosilanes (Si/C/H); 3.2.4 Oxygen-Containing Compounds (Si/C/H/O); 3.2.5 Nitrogen-Containing Compounds (Si/C/H/N); 3.2.6 Di- and Trisilicon-Containing Compounds; 3.2.7 Other Organosilicon Compounds; 3.3 Bond Dissociation Enthalpies and Free Radicals; 3.3.1 General Comments; 3.3.2 Directly Measured Values; 3.3.3 Derived Bond Dissociation Enthalpies; 3.4 Other Silicon-Containing Species; 3.4.1 Silylenes; 3.4.1.1 SiX2 molecules; 3.4.1.2 SiHX molecules; 3.4.2 [pi]-Bonded Species; 3.5 Appendix; 3.6 Conclusion; References
- 4 UV-Photoelectron Spectroscopy of Organosilicon Compounds4.1 Introduction; 4.2 Ultraviolet-Photoelectron Spectroscopy Instrument for Gas Phase Characterization; 4.2.1 Theoretical Background; 4.2.2 Description of Apparatus; 4.2.2.1 Classical ultraviolet-photoelectron spectroscopy (simple characterization); 4.2.2.2 Improvements; 4.2.2.3 Ultraviolet-photoelectron spectroscopy/mass spectrometry tandem (double characterization); 4.2.3 Coupling Ultraviolet-Photoelectron Spectroscopy Characterization with Synthesis Methods; 4.2.3.1 Flash vacuum thermolysis/ultraviolet-photoelectron spectroscopy
- 4.2.3.2 Vacuum gas solid reaction/ultraviolet-photoelectron spectroscopy4.2.3.3 Gas phase reaction/ultraviolet-photoelectron spectroscopy; 4.2.3.4 Photolysis/ultraviolet-photoelectron spectroscopy; 4.3 Theoretical Methods for Ionization Energy Calculation; 4.3.1 Hartree-Fock-Koopmans' Theorem; 4.3.2 Density Functional Theory-Janak's Theorem; 4.3.3 [delta]SCF (HF or KS) Methods; 4.3.4 Electron Perturbation Theory-Outer Valence Green's Function and P3 Methods; 4.3.5 Post-Hartree-Fock and Related Methods; 4.3.6 Time-Dependent Density Functional Theory; 4.3.7 Corrected Methods