Frustrated Lewis pairs /
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| Imprint: | Cham, Switzerland : Springer, [2021] |
|---|---|
| Description: | 1 online resource (viii, 404 pages) |
| Language: | English |
| Series: | Molecular Catalysis ; v.2 Molecular Catalysis ; v. 2. |
| Subject: | |
| Format: | E-Resource Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/12609152 |
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| 245 | 0 | 0 | |a Frustrated Lewis pairs / |c J. Chris Slootweg, Andrew R. Jupp, editors. |
| 264 | 1 | |a Cham, Switzerland : |b Springer, |c [2021] | |
| 300 | |a 1 online resource (viii, 404 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file | ||
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| 490 | 1 | |a Molecular Catalysis ; |v v.2 | |
| 520 | |a This volume highlights the latest research in frustrated Lewis pair (FLP) chemistry and its applications. The contributions present the recent developments of the use of FLPs in asymmetric catalysis, polymer synthesis, homogeneous and heterogeneous catalysis, as well as demonstrating their use as a pedagogical tool. The book will be of interest to researchers in academia and industry alike. | ||
| 588 | |a Description based on online resource; title from digital title page (viewed on January 28, 2021). | ||
| 505 | 0 | |a Intro -- Preface -- Contents -- 1 Frustrated Lewis Pair Catalysis: An Introduction -- 1.1 Introduction -- 1.2 FLP Hydrogenations -- 1.2.1 The Beginning -- 1.2.2 Broadening the Substrate Scope -- 1.2.3 Functional-Group Tolerance -- 1.2.4 Catalyst Variation -- 1.2.5 Heterogeneous Hydrogenation Catalysis -- 1.2.6 Asymmetric Hydrogenation -- 1.3 Other Catalysis with FLPs -- 1.3.1 Hydrosilylation -- 1.3.2 Transfer Hydrogenation -- 1.3.3 Hydroboration -- 1.3.4 Amination -- 1.3.5 Hydroarylation -- 1.3.6 C-H Borylation -- 1.3.7 Polymerization -- 1.3.8 CO2 Reduction -- 1.3.9 C-F Derivatization | |
| 505 | 8 | |a 1.4 Future Directions -- References -- 2 Frustrated Lewis Pair Catalyzed Asymmetric Reactions -- 2.1 Introduction -- 2.2 Asymmetric Hydrogenation -- 2.2.1 Asymmetric Hydrogenation of Imines and Related Substrates -- 2.2.2 Asymmetric Hydrogenations of N-Heterocyclic Compounds -- 2.2.3 Asymmetric Hydrogenations of Silyl Enol Ethers -- 2.2.4 Asymmetric Hydrogenations of Ketones and Enones -- 2.3 Asymmetric Hydrosilylation -- 2.4 Asymmetric Transfer Hydrogenation -- 2.5 Miscellaneous -- 2.6 Summary -- References -- 3 FLP Reduction of Carbon Monoxide and Related Reactions -- 3.1 Introduction | |
| 505 | 8 | |a 3.2 Synergic FLP Binding to NO, CO, and Related Molecules -- 3.3 Metal-Free FLP Reduction and Coupling of Carbon Monoxide -- 3.4 Reaction of P/B/B FLPs with Carbon Monoxide: Formation of Macrocyclic Oligomers -- 3.5 Reaction of Carbon Monoxide at d0-Metallocene Cations -- 3.6 Conclusions -- References -- 4 FLP-Mediated C-H-Activation -- 4.1 Introduction -- 4.2 C-H Functionalization by Transition Metal Complexes -- 4.3 FLP Transformations: A Kinetic Concept -- 4.4 Functionalization of C-H Bonds Through Electrophilic Activation -- 4.4.1 Electrophilic Borylation Starting from Haloboranes | |
| 505 | 8 | |a 4.4.2 Electrophilic Borylation Starting from Hydroboranes -- 4.4.3 Electrophilic Silylation -- 4.5 Concerted Activation by FLPs -- 4.5.1 Activation of Alkenes and Alkynes -- 4.5.2 Activation of Alkanes -- 4.6 Catalytic C-H Borylation by FLPs -- 4.6.1 C-H Activation of Arenes with Aminoborane FLPs -- 4.6.2 Towards Practical Metal-Free C-H Borylation Methodologies -- 4.7 Isodesmic Borylation: Auto-Assembled FLPs -- 4.8 Frustrated Lewis Radicals -- 4.9 Concluding Remarks -- References -- 5 Mechanistic Insight into the Hydrogen Activation by Frustrated Lewis Pairs -- 5.1 Introduction | |
| 505 | 8 | |a 5.2 Types of FLPs -- 5.2.1 Boron and Aluminum as Lewis Acid Centers -- 5.2.2 Nitrogen, Phosphorus, and Oxygen as Lewis Base Centers -- 5.3 Mechanistic Studies Using DFT Calculations -- 5.3.1 LA-LB Complexation -- 5.3.2 Transition State and Reaction Kinetics -- 5.3.3 Engineering FLP Reactivity -- 5.3.4 Ethereal Solvents as Lewis Bases -- 5.3.5 The Role of Water Molecules -- 5.4 Mechanistic Studies Using AIMD Simulation -- 5.4.1 Transition State Characterization by Ab Initio Molecular Dynamics Simulations -- 5.4.2 AIMD Simulation of Solvated Ion-Pairs | |
| 500 | |a Includes index. | ||
| 650 | 0 | |a Lewis acids. |0 http://id.loc.gov/authorities/subjects/sh89004433 | |
| 650 | 0 | |a Catalysis. |0 http://id.loc.gov/authorities/subjects/sh85020938 | |
| 650 | 7 | |a Lewis acids. |2 fast |0 (OCoLC)fst00996997 | |
| 650 | 7 | |a Catalysis. |2 fast |0 (OCoLC)fst00848867 | |
| 650 | 7 | |a Chemistry, Inorganic. |2 fast |0 (OCoLC)fst00853488 | |
| 650 | 7 | |a Chemistry, Organic. |2 fast |0 (OCoLC)fst00853501 | |
| 650 | 7 | |a Chemistry, Physical and theoretical. |2 fast |0 (OCoLC)fst00853521 | |
| 655 | 4 | |a Electronic books. | |
| 700 | 1 | |a Slootweg, J. Chris, |e editor. | |
| 700 | 1 | |a Jupp, Andrew R., |e editor. | |
| 776 | 0 | 8 | |i Print version: |z 3030588874 |z 9783030588878 |w (OCoLC)1182844918 |
| 830 | 0 | |a Molecular Catalysis ; |v v. 2. | |
| 903 | |a HeVa | ||
| 929 | |a oclccm | ||
| 999 | f | f | |i 4f3e80ab-0841-5a1f-b8fa-889a615ebd99 |s 0287af95-09bb-5bfe-8216-e87ef5d4ab27 |
| 928 | |t Library of Congress classification |a QD262 .F78 2021 |l Online |c UC-FullText |u https://link.springer.com/10.1007/978-3-030-58888-5 |z Springer Nature |g ebooks |i 12624760 | ||