Scorpionates : the coordination chemistry of polypyrazolylborate ligands /
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| Author / Creator: | Trofimenko, Swiatoslaw. |
|---|---|
| Imprint: | London : Imperial College Press ; River Edge, NJ :Distributed by World Scientific Pub., c1999. |
| Description: | x, 282 p. : ill. ; 23 cm. |
| Language: | English |
| Subject: | |
| Format: | Print Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/4062371 |
Table of Contents:
- 1. Introduction
- 1.1. General Considerations
- 1.2. Polypyrazolylborates--Scorpionates
- 1.3. The Abbreviation System for Scorpionate Ligands
- 1.4. Comparison of the Tp and Cp Ligands
- 1.5. Historical Development
- 1.6. Reviews
- 1.7. Synthesis of Scorpionate Ligands
- 1.8. List of Known Scorpionate Ligands
- 1.9. Analogs of Scorpionate Ligands
- 2. Homoscorpionates--First Generation
- 2.1. General Considerations
- 2.2. Group 1: H, Li, Na, K, Rb and Cs
- 2.3. Group 2: Be, Mg, Ca, Sr, Ba
- 2.4. Group 3: Sc, Y
- 2.5. Group 4: Ti, Zr, Hf
- 2.6. Group 5: V, Nb, Ta
- 2.7. Group 6: Cr, Mo, W
- 2.8. Group 7: Mn, Tc, Re
- 2.9. Group 8: Fe, R, Os
- 2.10. Group 9: Co, Rh, Ir
- 2.11. Group 10: Ni, Pd, Pt
- 2.12. Group 11: Cu, Ag, Au
- 2.13. Group 12: Zn, Cd, Hg
- 2.14. Group 13: B, Al, Ga, In, Tl
- 2.15. Group 14: C, Si, Ge, Sn, Pb
- 2.16. Group 15: N, P, As, Sb, Bi
- 2.17. Lanthanides
- 2.18. Actinides
- 3. Homoscorpionates--Second Generation
- 3.1. General Considerations
- 3.1.1.. Regiochemistry in Ligand Synthesis
- 3.1.2.. Quantification of Steric Effects in Tp[superscript x] Ligands
- 3.1.3.. Ligand Rearrangments
- 3.2. Individual Ligands
- 3.2.1.. B-substituted Ligands, RTp[superscript x] (R [not equal] pz[superscript x])
- 3.2.2.. 3-Monosubstituted Ligands, Tp[superscript R]
- 3.2.3.. 4-Monosubstituted Ligands, Tp[superscript 4R]
- 3.2.4.. 5-Monosubstituted Ligands, Tp[superscript 5R]
- 3.2.5.. C-Disubstituted Ligands
- 3.2.5.1. 3,4-Disubstituted Ligands
- 3.2.5.2a. 3,5-Disubstituted Ligands of Type Tp[superscript R2]
- 3.2.5.2b. 3,5-Disubstituted Ligands of Type Tp[superscript R,R']
- 3.2.5.3. 4,5-Disubstituted Ligands
- 3.2.6.. Trisubstituted Ligands
- 4. Heteroscorpionates, RR'Bp[superscript x]
- 4.1. General Considerations
- 4.2. Specific Ligands
- 4.2.1.. Bp[superscript x] Ligands
- 4.2.2.. R[subscript 2]Bp[superscript x] Ligands
- 4.3. Ligands R(R'Z)Bp[superscript x]
- 4.3.1.. General Considerations
- 4.3.2.. Specific Ligands
- 4.4. Pyrazaboles (= R[subscript 2]([mu]-pz[superscript x])[subscript 2]BR'[subscript 2])
- 4.4.1.. Symmetrical pyrazaboles
- 4.4.2. Unsymmetrical pyrazaboles
- 5. Applications of Scorpionate Ligands
- 5.1. General Considerations
- 5.2. Catalysis
- 5.2.1. Polymerization and Oligomerization
- 5.2.2. Carbene/Nitrene Transfer
- 5.2.3. Oxidation
- 5.2.4. Miscellaneous Catalysis
- 5.3. Enzyme Modelling
- 5.3.1. Vanadium
- 5.3.2. Molybdenum
- 5.3.3. Tungsten
- 5.3.4. Manganese
- 5.3.5. Iron
- 5.3.6. Nickel
- 5.3.7. Copper
- 5.3.8. Zinc
- 5.4. C--H Bond Activation
- 5.5. Metal Deposition
- 5.6. Metal Extraction
- 5.7. Miscellaneous Studies
- 5.8. Concluding Remarks
- References
- Index
