Organosilicon chemistry IV : from molecules to materials /

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Bibliographic Details
Imprint:Weinheim ; Chichester : Wiley-VCH, 2000.
Description:xviii, 834 p. : ill. ; 25 cm.
Language:English
Subject:
Format: Print Book
URL for this record:http://pi.lib.uchicago.edu/1001/cat/bib/4235368
Hidden Bibliographic Details
Varying Form of Title:Organosilicon chemistry four
Organosilicon chemistry 4
Other authors / contributors:Weis, Johann.
Auner, Norbert.
ISBN:3527298541
Notes:Includes bibliographical references and index.
Table of Contents:
  • Introduction
  • Silicon Biotechnology: Proteins, Genes and Molecular Mechanisms Controlling Biosilica Nanofabrication Offer New Routes to Polysiloxane Synthesis
  • Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements
  • Influence of Substituted Trimethoxysilanes on the Synthesis of Mesostructured Silica Materials
  • Biocatalysis in Preparative Organosilicon Chemistry: Microbial Reduction of rac-1-(4-Fluorophenyl)-1-methyl-1-sila-2-cyclohexanone and Microbial Hydrolysis of rac-(Sis,CR/SiR,CS)-2-Acetoxy-1-(4-fluorophenyl)-l-methyl-l-silacyclohexane
  • Preparation of Silicon- and Germanium-Containing [alpha]-Amino Acids
  • Fascinating Silicon-Chemistry--Retrospection and Perspectives
  • Raman Spectra of Molecular SiS[subscript 2] and GeS[subscript 2] in Solid CH[subscript 4]
  • The Quest for Silaketene
  • Donor-Substituted Silylenes: From Gas-Phase Reactions to Stable Molecules
  • Different Reactivities of Divalent Silicon Compounds Towards Metallocene Derivatives of Molybdenum and Tungsten
  • Reactions of Decamethylsilicocene with Inorganic and Organometallic Main Group Element Compounds
  • Unusual Silylene Reactions with M(II) Compounds (M = Ge, Sn or Pb)
  • Silylene and Disilene Reactions with some 1,3-Dienes and Diynes
  • Sterically Overloaded Silanes, Silylenes and Disilenes with Supersilyl Substitutents tBu[subscript 3]Si
  • A New Conformational Polymorph of Solid Tetramesityldisilene Mes[subscript 2]Si-SiMes[subscript 2], found by Raman, UV-Vis and Fluorescence Spectroscopy
  • Synthesis and Reactivity of Unsaturated Tin Compounds: Me[subscript 2]Sn=C(SiMe[subscript 3])[subscript 2] and Me[subscript 2]Sn=N(SitBu[subscript 2]Me)
  • The Si[subscript 4]H[subscript 6] Potential Energy Surface
  • Hexaaryltetrasilabuta-1,3-diene: Synthesis and some Reactions
  • Products of the Reaction of Tetrasupersilyl-tetrahedro-tetrasilane (tBu[subscript 3]Si)[subscript 4]Si[subscript 4] with Iodine
  • Intramolecularely [pi]-Stabilized Silyl Cations
  • Silyl Effects in Hypercoordinated Carbocations
  • Silyl Stabilization in Cyclopropylmethyl Cations: NMR-Spectroscopic and Quantum Chemical Results
  • N,O-Dimethyl-N-silylhydroxylamine, a Compound with Steeply Pyramidal Nitrogen Coordination
  • Strong [beta]-Donor-Acceptor Bonds in Hydroxylaminosilanes
  • [beta]-Donor Bonds in Hydroxylamino- and Oximatosilanes
  • Synthesis and Rotational Isomerism of Some Iodosilanes and Iododisilanes
  • The Rotational Isomerism of the Disilanes tBuX[subscript 2]SiSiX[subscript 2]tBu (X = Cl, Br and I): A Combined Raman Spectroscopic, X-Ray Diffraction and Ab Initio Study
  • The Rotational Isomerism of the Disilanes MeX[subscript 2]SiSiX[subscript 2]Me (X = H, F, Br and I): A Combined Ab Initio and Raman Spectroscopic Study
  • The Rotational Isomerism of F[subscript 3]CSiMe[subscript 2]SiMe[subscript 2]CF[subscript 3]: Do Three Conformers Exist in the Liquid state?
  • Formation, Stability and Structure of Aminosilane-Boranes
  • Hydrosilylation and Hydroboration of Indene--a Comparison
  • Gallium-Silicon Heterocycles
  • Novel Silaheterocycles by Carbenoid and Diazo Reactions
  • Synthesis and Reactivity of Novel 1,2-Disilacyclopentanes
  • Synthesis of Heavily Halogenated Vinylsilanes
  • Electrochemical Formation of Silicon-Carbon Bonds
  • Heteroaromatic-Substituted Silanes--Synthesis, Lithium Derivatives and Anionic Rearrangements
  • Iodo Trimethylsilylmethylene Triphenylphosphorane--a Molecule of Theoretical and Synthetic Interest
  • Silole-Containing [pi]-Conjugated Systems: Synthesis and Application to Organic Light-Emitting Diodes
  • Silylhydrazines: Lithium Derivatives, Oxidation and Condensation Reactions
  • Cyclosilazanes with SiH[subscript 2], SiHal[subscript 2], Si(Hal)NH[subscript 2] Groups--Experiments and Molecular Orbital Ab Initio Calculations
  • Iminosilanes: Precursors of New Rings and Unknown Ring Systems
  • Silazanes Derived from Trichlorosilane: Syntheses, Reactions and Structures
  • Bis(trimethylsilyl)diaminosilanes: Synthesis and Reactions
  • Influence of the Steric Demand of Lithium Trialkylsilylamides, -phosphanides and -arsanides on the Metathesis Reaction with Tris(trimethylsilyl)methylzinc Chloride
  • Silicon and Germanium Amidinates
  • Insertion of Aromatic Diisocyanates into the N-Si Bonds of 1,4-Bis(trimethylsilyl)- 1,4-dihydropyrazine
  • Novel Bis(1,2-N,N-Dimethylaminomethylferrocentyl)-Silyl Compounds
  • Synthesis of Silicon Synthons for a Selective Oligomer Design
  • Synthesis and Characterization of New Precursors Based on Organosilicon for Construction of Porous Solid Structures
  • Synthesis and Structures of Stable Aminosilanes and their Metal Derivatives: Building Blocks for Metal-Containing Nitridosilicates
  • Octachlorocyclotetrasilane, Perchloropolysilane and New Dialkoxy- and Diaminopolysilanes
  • Polysilyl Dianions--Synthesis and Reactivity
  • Synthesis and Reactions of Chlorinated Oligosilanes
  • Base-Catalyzed Disproportionation of Tetrachlorodimethyldisilane--Investigations of the Heterogeneous Catalysts
  • Synthesis of Linear and Cyclic Bis(trimethylsilyl)aminooligosilanes
  • Synthesis and Functionalization of Branched Oligosilanes
  • Geminal Di(hypersilyl) Compounds: Synthesis, Structure and Reactivity of some Sterically Extremely Congested Molecules
  • The Acid-Induced Rearrangement of [alpha]-Functionalized Alkylpolysilanes
  • Hypersilyl Compounds of Elements of Group 15
  • [superscript 29]Si-MAS-NMR Investigations of Amino-Substituted Chloromethylpolysilanes
  • Investigation of the Longitudinal Relaxation Time T[subscript 1] of Silanes
  • Ferrocene as a Donor in Dipolar Oligosilane Structures
  • Siloxene-Like Polymers: Networks
  • Silicon-Containing Spacers for the Synthesis of Tin-Containing Multidentate Lewis Acids
  • Six-membered Stannyloligosilane Ring Systems--One Ring Size, Different Combination Pattern
  • Structure and Reactivity of Novel Stannasiloxane Complexes
  • Control of Distannoxane Structure by Silicon-Containing Spacers
  • The Influence of Intramolecular Coordination and Ring Strain on the Polymerization Potential of Cyclic Stannasiloxanes
  • Unconventional Solvents for Hydrolysis of Tetramethoxysilane
  • Reactions of Siloxysilanes with Alkali Metal Trimethylsilanolates
  • Cyclopentadienyl (Cp)-Substituted Silanetriols and Novel Titanasiloxanes as Condensation Products
  • Metal-Fragment Substituted Disilanols
  • Dicobaltoctacarbonyl-Assisted Synthesis of Ferriosilanols
  • Novel Silanols and Siloxanes Substituted with the Ferriomethyl Fragment Cp(OC)[subscript 2]FeCH[subscript 2]
  • Cyclosiloxanes with Si-Si-O and Si-O Groups
  • Syntheses, Structures, and Properties of Zwitterionic Monocyclic [lambda superscript 5]Si-Silicates
  • Isomerization of Chiral Zwitterionic Monocyclic [lambda superscript 5]Si-Silicates
  • Zwitterionic Spirocyclic [lambda superscript 5]Si-Silicates Containing Diolato(2-) Ligands Derived from Acetohydroximic Acid and Benzohydroximic Acid
  • Isoelectronic Zwitterionic Pentacoordinate Silicon Compounds with SiO[subscript 4]C and SiO[subscript 5] Frameworks
  • The Zwitterionic Spirocyclic [lambda superscript 5]Si-Silicate [(Dimethylammonio)methyl]bis-[salicylato(2-)-O superscript 1, O superscript 3]silicate: Experimental and Computational Studies
  • Oxygen, Phosphorus or Sulfur Donor Ligands in Higher-Coordinated Organosilyl Chlorides and Triflates
  • Coupling Constants through a Rapidly Dissociating-Recombining N[right arow]Si Dative Bond in Pentacoordinate Silicon Chelates
  • Salen-Silicon Complexes--a New Type of Hexacoordinate Silicon
  • Photoluminescence of Organically Modified Cyclosiloxanes
  • Octasilsesquioxanes as Traps for Atomic Hydrogen at Room Temperature
  • Highly Functionalized Octasilsesquioxanes Synthesis, Structure and Reactivity
  • Synthesis and Characterization of Chloro-, Allyl- and Ferrocenyl- Substituted Silsesquioxanes
  • Octakis(Dimethylphosphinoethyl)octasilasesquioxane: Synthesis, Characterization and Reactivity
  • Synthesis of Homo- and Mixed-Functionalized Octa-, Deca- and Dodeca-Silsesquioxanes by Cage Rearrangement and their Characterization
  • Synthesis of Polyhedral Hexa-, Octa-, Deca- and Dodeca-Silsesquioxanes Separation by NP-HPLC, SEC and LAC Characterization by MALDI-TOF-MS
  • Mixed Functionalized Octa(organylsilsesquioxanes) with Different Side Chains as Ligands for Metal Complexes
  • Polymerization of Silanes with Platinum Metal Catalysts
  • Polymorphism and Molecular Mobility of Poly(silane)s and Poly(silylenemethylene)s
  • Synthesis, Functionalization and Cross-Linking Reactions of Poly(silylenemethylene)s
  • Highly Branched Polycarbosilanes: Preparation, Structure, and Functionality
  • Photoconductivity of C[subscript 60]-doped Poly(disilanyleneoligothienylene)s
  • Application of Functionalized Polysilanes in Organic Light-Emitting Diodes
  • Commercial Hybrid Organic-Inorganic Polymers
  • Inorganic-Organic Copolymers--Materials with a High Potential for Chemical Modification
  • High Performance Silicon Polymer with Organoboron Structure
  • Polydimethylsiloxane (PDMS): Environmental Fate and Effects
  • Silicones for the Textile Industry
  • Poly-Functionalization of Polysiloxanes--New Industrial Opportunities
  • The Use of a Silicone-Bonded Azo Dye as Chemical Proton Detector
  • New Insights in the Influence of Oxygen on the Photocrosslinking of Silicone Acrylates
  • Synthesis of New [alpha],[omega]-Olefinic Silicon-Containing Compounds via Cross-Metathesis
  • The Science of Building Materials and the Repair of Buildings: Masonry Protection with Silicones
  • What "Super" Spreads?--An Analysis of the Spreading Performance of the Single Components of the Trisiloxane Superspreader Type M[subscript 2]D-(CH[subscript 2])[subscript 3]-(OCH[subscript 2]CH[subscript 2])[subscript n]-OCH[subscript 3]
  • Trisiloxane Surfactants--Mechanisms of Spreading and Wetting
  • Silicone Rubbers Innovative--High Performance--Efficient
  • The Fine Art of Molding: Flexible Molds of RTV-2 Silicone Rubber
  • Molecular Reactors Based on Organosilicon [mu]-Networks
  • Fine Silica: From Molecule to Particle: Quantum Chemical Modeling and Vibration Spectra Verification
  • Fumed Silica Structure and Particle Aggregation: Computational Modeling and Verification by Vibrational Spectroscopy
  • Mechanical Behavior of Polydimethylsiloxanes under Deformation. Quantum-Chemical View
  • Intermolecular Interactions of Polydimethylsiloxane Oligomers with Hydroxylated and Silylated Fumed Silica: Quantum Chemical Modeling
  • Adsorption of Polydimethylsiloxane on Hydrophilic and Silylated Fumed Silica. Investigations by Differential Scanning Calorimetry
  • Initial and Silylated Silica Surfaces: Assessing Polydimethylsiloxane-Silica Interactions Using Adsorption Techniques
  • Modification of Porous Silicon Layers with Silanes
  • In-Situ Controlled Deposition of Thin Silicon Films by Hot-Filament MOCVD with (C[subscript 5]Me[subscript 5])Si[subscript 2]H[subscript 5] and (C[subscript 5]Me[subscript 4]H)SiH[subscript 3] as Silicon Precursors
  • The Synthesis of Cyclopentadienyl Silanes and Disilanes and their Fragmentation under Thermal CVD Conditions
  • Novel Silyl-Carbodiimide Gels for the Preparation of Si/C/(N) Ceramics
  • Thermodynamics, Kinetics and Catalysis in the System Ni-Si-H-Cl: Thermodynamic Description of Chlorine-Containing Silicides
  • Author Index
  • Subject Index