Introduction to non-linear kinetics in heterogeneous catalysis /
Saved in:
| Author / Creator: | Pyantaanitsky, Yuri I. |
|---|---|
| Imprint: | Huntington, N.Y. : Nova Science Publishers, c2000. |
| Description: | x, 190 p. : ill. ; 27 cm. |
| Language: | English |
| Subject: | |
| Format: | Print Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/4299598 |
Table of Contents:
- Ch. 1. Introduction. 1.1. Chemical Reaction Rate. 1.2. Rate of Heterogeneous Catalytic Reaction. 1.3. Plug Flow and Completely Mixed Methods of Measuring of the Rates of Heterogeneous Catalytic Reactions
- Ch. 2. Elementary Theory of Kinetics of Complex Steady-State Reactions. 2.1. Elementary Chemical Reactions and Stages. 2.2. Law of Active Surfaces. 2.3. Nonuniform Surface. Mutual Influence of Adsorbed Species. 2.4. Linear and Non-linear Elementary Reactions and Mechanisms of Complex Reactions. 2.5. Kinetic Equations (Kinetic Models) of Complex Reactions. 2.6. Stoichiometric Numbers, Reaction Routes, Steady-State Equations. 2.7. Graphs in Chemical Kinetics
- Ch. 3. Steady State Multiplicity. 3.1. Different Steady States for Identical External Conditions. 3.2. Strong Parametric Sensibility. 3.3. Multiplicity of Steady States Determined by the Kinetic Model of the Reaction. 3.4. Multiplicity of Equilibrium States in Adsorption
- Ch. 4. Self-Excited Oscillations in Heterogeneous Catalysis. 4.1. Reactions in a Gradientless Reactor. Stable and Unstable Stationary States. 4.2. Types of Feedback in Kinetic Oscillators
- Ch. 5. Kinetics of Competitive Heterogeneous Catalytic Reactions. 5.1. Competitive Reactions With the Same Mechanisms. 5.2. Reactions With the Same Initial Steps of Competitive Reagents - Catalyst Interaction. 5.3. Non-Trivial Mutual Influence of Competitive Reactions
- Ch. 6. Kinetics of Some Typical Heterogeneous Catalytic Reactions With Non-Linear Mechanisms. 6.1. Kinetics of Vapor-Phase Hydrogenation of Acetone on Metals. 6.2. Kinetics of Hydrogenation of Aliphatic Nitriles. 6.3. Kinetics of Hydrogenation of Carbon Monoxide. 6.4. Kinetics of Hydrogenation of Carbon Dioxide. 6.5. Hydrogenation of Acetylene at Elevated Temperatures. 6.6. Partial Oxidation of Aromatic Hydrocabons. 6.7. Kinetics of Ammonia Synthesis
- Ch. 7. Heterogenous-Homogeneous Reactions. 7.1. Heterogeneous-Homogeneous Chlorination of Methane. 7.2. Hydrogen Oxidation Reaction: Two Different Locations of the First Explosive Range. 7.3. Low-Temperature Benzene Oxidation on Platinum and Palladium. Multiplicity of Steady States. 7.4. Kinetics of Oxidative Coupling of Methane.
