Principles of pulse electron paramagnetic resonance /
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Author / Creator: | Schweiger, A. (Arthur) |
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Imprint: | Oxford, UK ; New York : Oxford University Press, 2001. |
Description: | xxvi, 578 p. : ill. ; 25 cm. |
Language: | English |
Subject: | |
Format: | Print Book |
URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/4561299 |
Table of Contents:
- Preface
- Acknowledgements
- Symbols
- Abbreviations
- 1. Introduction
- 1.1. Scope of pulse EPR
- 1.2. A short history of pulse EPR
- 1.3. Examples of applications
- 2. Classical Description
- 2.1. The resonance phenomenon
- 2.2. The vector picture for pulse EPR experiments
- 2.3. Relaxation and the Bloch equations
- 3. Spin Hamiltonian
- 3.1. Static spin Hamiltonian
- 3.2. Oscillatory Hamiltonian
- 3.3. Inhomogeneity in spin systems
- 3.4. Eigenvalues and eigenvectors of spin Hamiltonians
- 3.5. Model system for pulse EPR and ENDOR experiments
- 4. Density Operators and Their Evolution
- 4.1. Quantum mechanical description of the state of a spin system
- 4.2. Quantum mechanical description of the time evolution of spin systems
- 4.3. Initial state of the spin system
- 5. Spectral Analysis
- 5.1. The signal in time-domain spectroscopy
- 5.2. Methods for signal analysis
- 6. Manipulation of Electron and Nuclear Spins
- 6.1. Manipulating spin states and Hamiltonians
- 6.2. Tools
- 6.3. Building blocks for the generation, transfer and detection of polarization and coherence
- 6.4. Polarization transfer experiments
- 6.5. Electron coherence transfer experiments
- 6.6. Nuclear coherence transfer experiments
- 7. Two-Level Dynamics
- 7.1. Free induction decays
- 7.2. Electron spin echoes
- 7.3. Transient signals under microwave irradiation
- 7.4. Physics of transient signal detection
- 8. Relaxation and Related Phenomena
- 8.1. Relaxation processes
- 8.2. Basics of relaxation studies
- 8.3. Measurement of longitudinal relaxation times
- 8.4. Measurement of transverse relaxation times
- 8.5. Measurement of rotating-frame relaxation times
- 8.6. Nuclear spin relaxation
- 9. Fourier Transform EPR
- 9.1. Basics of Fourier transform EPR
- 9.2. Transient FT EPR
- 9.3. Two-dimensional FT EPR
- 10. Nuclear Modulation Effect I: Basic Experiments
- 10.1. Two-pulse ESEEM and general ESEEM theory
- 10.2. Three-pulse ESEEM
- 10.3. Hyscore
- 11. Nuclear Modulation Effect II: Advanced Methods
- 11.1. Deadtime and blind-spot free ESEEM methods
- 11.2. ESEEM experiments with improved sensitivity
- 11.3. Soft ESEEM
- 11.4. Nuclear coherence-transfer experiments in one dimension
- 11.5. Nuclear coherence-transfer experiments in two dimensions
- 11.6. Hole-burning experiments
- 11.7. Extended-time excitation experiments
- 11.8. Special two-dimensional experiments
- 12. Pulse Endor
- 12.1. Basic principles
- 12.2. ENDOR experiments based on polarization transfers
- 12.3. Coherence-transfer ENDOR
- 12.4. Time-domain ENDOR
- 12.5. Hyperfine-correlated ENDOR spectroscopy
- 13. Pulse Eldor and Related Experiments
- 13.1. Two-frequency versus field-step ELDOR
- 13.2. Polarization-transfer ELDOR
- 13.3. Measurement of electron-electron couplings
- 14. Transient Nutation Techniques
- 14.1. Parameter extraction from nutation frequencies
- 14.2. Experimental techniques
- 15. Field-Swept EPR Experiments in One and Two Dimensions
- 15.1. One-dimensional experiments
- 15.2. Two-dimensional experiments
- 16. Other Techniques
- 16.1. EPR imaging and other spatially resolved techniques
- 16.2. The linear electric field effect
- 16.3. Multiple photon resonance in pulse EPR
- 16.4. Self-induced transparency
- 16.5. Dark resonance and electromagnetically induced transparency
- 16.6. EPR with stochastic excitation
- 16.7. Alternative detection schemes
- 17. Multi-Frequency EPR
- 17.1. Choice of the optimum EPR frequency
- 17.2. High-frequency EPR
- 18. Application Aspects
- 18.1. EPR parameters and aspects of structure and dynamics
- 18.2. Experimental strategies for obtaining EPR parameters
- Appendix A. Sign Conventions
- Appendix B. Mathematics
- Appendix C. Experimental Aspects
- References
- Index