Nonequilibrium nondissipative thermodynamics : with application to low-pressure diamond synthesis /
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| Author / Creator: | Wang, Ji-Tao, 1933- |
|---|---|
| Imprint: | Berlin ; New York : Springer, 2002. |
| Description: | xii, 254 p. : 114 fig. ; 25 cm. |
| Language: | English |
| Series: | Springer series in chemical physics. v. 68. |
| Subject: | |
| Format: | Print Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/4619968 |
Table of Contents:
- 1. Classical Thermodynamics
- 1.1. Basic Laws of Classical Thermodynamics
- 1.2. Classical Equilibrium Thermodynamics
- 1.3. Nonequilibrium Thermodynamics in Classical Thermodynamics
- 1.4. Criteria of Change Direction and Limitation
- 1.5. Relationship Between Gibbs Free Energy and Temperature or Pressure
- 1.6. Chemical Potential and Its Relationship with Temperature and Pressure
- 1.7. Change of Gibbs Free Energy in Chemical Reactions
- 1.8. Limitation to the Applicability of Classical Thermodynamics
- 2. Fundamentals of Modern Thermodynamics
- 2.1. Modern Formulation of Basic Thermodynamic Laws
- 2.2. Some Basic Concepts in Nonequilibrium Thermodynamics
- 2.2.1. Irreversibility of Change with Time
- 2.2.2. Equilibrium State, Stationary State and Nonequilibrium State
- 2.2.3. Reversible and Irreversible Processes
- 2.1. Assumption of Local Equilibrium
- 2.2. Calculation of Entropy
- 2.3. Systematization of Modern Thermodynamics
- 2.4. Onsager's Reciprocity Relation
- 2.5. Entropy Production Minimization Principle
- 2.6. Prigogine's Dissipative Structures
- 2.8.1. Bénard's Pattern
- 2.8.2. Laser Emission
- 2.8.3. Chemical Oscillation
- 3. High-Pressure Synthesis and Low-Pressure Vapor Growth of Diamond Seeds
- 3.1. Early History of Diamond Synthesis
- 3.2. Thermodynamic Predictions
- 3.3. Success of the High-Pressure Process
- 3.4. Early Exploration of Low-Pressure Vapor Growth of Diamond Seeds
- 3.5. Thermodynamic Conditions for Crystal Growth from the Vapor Phase
- 3.5.1. Supersaturation Degree
- 3.5.2. Nucleation Barrier
- 3.6. Diamond Seed Growth from the Vapor Phase
- 4. Activated Low-Pressure Diamond Growth from the Vapor Phase
- 4.1. Success of Activated Low-Pressure Vapor Growth Process
- 4.2. Setup of Activated Low-Pressure Growth from the Vapor Phase
- 4.3. Preferential Etching Kinetic Model of SAH
- 4.4. Kinetic Control Model
- 4.5. Some Thermodynamic Theoretical Models of the 1980s
- 4.5.1. Quasiequilibrium Model
- 4.5.2. Surface Reaction Thermodynamic Model
- 4.5.3. Defect-Induced Stabilization Model
- 5. Reaction Coupling Model
- 5.1. Chemical Pump Model
- 5.1.1. Mechanism of the Chemical Pump
- 5.1.2. Chemical Pump Reaction
- 5.1. Calculation of the Chemical Pump Effect
- 5.2. Reaction Coupling Model
- 5.3. Thermodynamic Data for Activated Graphite
- 5.4. New Concept of Nonequilibrium (Stationary) Phase Diagrams
- 5.5. Nonequilibrium Nondissipation Principle
- 5.6. Calculation of Nonequilibrium Phase Diagrams
- 5.7. Some Results and Discussions
- 5.8. Morphology of Diamond Crystals and Orientation of Diamond Films
- 6. Nonequilibrium Phase Diagrams of C-H, C-O and Other Binary Systems
- 6.1. T-X Nonequilibrium Phase Diagrams for C-H Binary Systems
- 6.2. T-p-X Nonequilibrium Phase Diagrams for C-H and C-O Binary Systems
- 6.3. Nonequilibrium Phase Diagrams for Other Binary Systems
- 7. Nonequilibrium Phase Diagrams of C-H-O and Other Ternary Systems
- 7.1. Bachmann's Empirical Phase Diagram for the C-H-O System
- 7.2. Projective Nonequilibrium Phase Diagrams for C-H-O Systems
- 7.3. Influences of T and p Ranges on C-H-O Ternary Phase Diagrams
- 7.4. Cross-Sectional Nonequilibrium Phase Diagrams for C-H-O Ternary Systems
- 7.5. Nonequilibrium Phase Diagrams for C-H-X Ternary Systems
- 8. Further Discussions on Some Debates
- 8.1. Coupled Reaction in Biochemistry
- 8.2. The Seventy-Year Controversy About Reaction Coupling in Chemistry
- 8.3. Quantitative Verification of Reaction Coupling in Inanimate Systems
- 8.4. Reaction Barrier in Synthetic Diamond Processes
- 8.4.1. """"Unified Barrier"""" Model
- 8.4.2. Thermodynamic Coupling Effect and Catalytic Effect
- 8.4.3. Analysis of Calculated Results and Conclusions
- 8.5. Other Thermodynamic Discussions on Activated CVD Diamond
- 8.5.1. Charged Cluster Model
- 8.5.2. Other Thermodynamic Discussions
- 9. Other Applications and Summary
- 9.1. Nonequilibrium Phase Diagrams for the Activated CVD cBN Process
- 9.2. Modern Thermodynamics for Belousov-Zhabotinsky Reactions
- 9.3. A Characteristic of Life: Drawing Negative Entropy from its Environment
- 9.4. Some Similarities of Reaction Coupling in Biological and Inanimate Systems
- 9.5. Some Conclusions, Further Development and Prospects
- References
- Index
