Structured fluids : polymers, colloids, surfactants /
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Author / Creator: | Witten, T. (Thomas A.) |
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Imprint: | Oxford ; New York : Oxford University Press, 2004. |
Description: | xiv, 216 p. : ill. ; 26 cm. |
Language: | English |
Subject: | |
Format: | Print Book |
URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/5136200 |
Table of Contents:
- 1. Overview
- 1.1. Introduction
- 1.2. A gallery of structured fluids
- 1.2.1. Self-organization
- 1.2.2. Rheology
- 1.2.3. Scaling
- 1.3. Types of structured fluids
- 1.3.1. Colloids
- 1.3.2. Aggregates
- 1.3.3. Polymers
- 1.3.4. Surfactant assemblies
- 1.3.5. Association
- 1.4. The chapters to follow
- References
- 2. Fundamentals
- 2.1. Statistical physics
- 2.1.1. Thermal equilibrium
- 2.1.2. Probability and work
- 2.1.3. Lattice gas
- 2.1.4. Approach to equilibrium
- 2.2. Magnitude of a liquid's response
- 2.3. Experimental probes of structured fluids
- 2.3.1. Macroscopic responses
- 2.3.2. Probes of spatial structure
- 2.3.3. Probes of atomic environment
- Solution to Problem 2.1
- References
- 3. Polymer molecules
- 3.1. Types of polymers
- 3.1.1. Monomers
- 3.1.2. Architecture
- 3.1.3. Polymerization
- 3.2. Random-walk polymer
- 3.2.1. End-to-end probability
- 3.3. Interior structure
- 3.3.1. Scattering
- 3.4. Self-avoidance and self-interaction
- 3.4.1. Local and global avoidance
- 3.4.2. Estimating D
- 3.4.3. Self-interaction and solvent quality
- 3.4.4. Universal ratios
- 3.4.5. Polyelectrolytes
- Appendix A. Dilation symmetry
- Appendix B. Polymeric solvents and screening
- References
- 4. Polymer solutions
- 4.1. Dilute solutions
- 4.2. Semidilute solutions
- 4.2.1. Structure
- 4.2.2. Energy
- 4.2.3. Concentrated solutions and melts
- 4.3. Motion in a polymer solution
- 4.3.1. Brownian motion of a sphere
- 4.3.2. Intrinsic viscosity
- 4.3.3. Polymer in dilute solution: hydrodynamic opacity
- 4.3.4. Internal fluctuations
- 4.3.5. Hydrodynamic screening
- 4.3.6. Semidilute diffusion
- 4.3.7. Semidilute self-diffusion without entanglement
- 4.3.8. Motion with entanglements
- 4.3.9. Stress relaxation and viscosity
- 4.4. Conclusion
- Appendix A. Origin of the Oseen tensor
- Solution to Problem 4.5 (Deriving permeability)
- References
- 5. Colloids
- 5.1. Attractive forces: why colloids are sticky
- 5.1.1. Induced-dipole interactions
- 5.1.2. Solid bodies
- 5.1.3. Perturbation-Attraction Theorem
- 5.1.4. Depletion forces
- 5.2. Repulsive forces
- 5.2.1. Steric stabilization
- 5.2.2. Electrostatic stabilization
- 5.3. Organized states
- 5.3.1. Colloidal crystals
- 5.3.2. Lyotropic liquid crystals
- 5.3.3. Fractal aggregates
- 5.3.4. Anisotropic interactions
- 5.4. Colloidal motion
- 5.4.1. Electrophoresis
- 5.4.2. Soret effect
- Appendix A. Perturbation attraction in a square-gradient medium
- Appendix B. Colloidal aggregates
- References
- 6. Interfaces
- 6.1. Probes of an interface
- 6.2. Simple fluids
- 6.2.1. Interfacial energy
- 6.2.2. Contact angle
- 6.2.3. Wetting dynamics
- 6.2.4. Surface heterogeneity
- 6.2.5. Other interfacial flows
- 6.3. Solutes and interfacial tension
- 6.3.1. Fluid mixtures
- 6.4. Polyatomic solutes
- 6.4.1. Polymer adsorption
- 6.4.2. Concentration profile
- 6.4.3. Hard wall
- 6.4.4. Kinetics of adsorption
- 6.4.5. Surface interaction
- 6.4.6. Flow
- 6.5. Conclusion
- References
- 7. Surfactants
- 7.1. Introduction
- 7.2. Mixing principles
- 7.2.1. Positivity
- 7.2.2. Additivity
- 7.2.3. Ordering: like dissolves like
- 7.2.4. Reciprocity
- 7.2.5. Transitivity
- 7.2.6. Effect of permanent dipoles: water
- 7.2.7. Effect of charges: ionic separation
- 7.3. Surfactant molecules
- 7.4. Surfactants in solution: micelles
- 7.4.1. Open aggregation: wormlike micelles
- 7.4.2. Open aggregation: two-dimensional micelles
- 7.4.3. Aggregation kinetics
- 7.5. Micelle interaction
- 7.5.1. Energy of two-dimensional micelles
- 7.5.2. Energy to confine a fluctuating membrane
- 7.6. Mixing immiscible liquids: microemulsions
- 7.6.1. Interfacial tension
- 7.6.2. Emulsions and foams
- 7.7. Amphiphilic polymers
- 7.7.1. Micelle size
- 7.7.2. Other copolymers
- 7.7.3. Polymeric amphiphiles in solution
- 7.8. Dynamics and rheology
- 7.8.1. Wormlike entanglement and relaxation
- 7.8.2. Rheology of lamellar solution
- 7.8.3. Shear-induced restructuring
- Appendix. Gauss-Bonnet Theorem
- References
- Index