Chemical kinetics and inorganic reaction mechanisms /
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| Author / Creator: | Ašperger, Smiljko. |
|---|---|
| Uniform title: | Kemijska kinetika i anorganski reakcijski mehanzmi. English |
| Edition: | 2nd ed. |
| Imprint: | New York : Kluwer Academic/Plenum Publishers, c2003. |
| Description: | xvii, 361 p. : ill. ; 26 cm. |
| Language: | English |
| Subject: | |
| Format: | Print Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/5171990 |
Table of Contents:
- Introduction
- 1.. Chemical kinetics and reaction mechanisms
- 1.1.. Introduction
- 1.2.. Chemical reactions and energy changes
- 1.3.. Collision theory
- 1.3.1.. Calculation of rate constants
- 1.3.2.. Arrhenius equation
- 1.4.. Transition state theory
- 1.5.. Steric effects and reactivity of strictly oriented molecules
- 1.5.1.. Molecular beams studies
- 1.5.2.. Symmetric top molecules
- 1.6.. Reaction energy profiles and the reaction coordinate
- 1.7.. Bimolecular and unimolecular nucleophilic substitutions (S[subscript N]2 and S[subscript N]1 substitutions)
- 1.8.. Novel views on the mechanism of bimolecular substitutions in the gas phase
- 1.9.. Classification of reaction mechanisms in inorganic chemistry involving metal complexes (D, A, I[subscript d] and I[subscript a] mechanisms)
- 1.9.1.. The collision theory in solutions
- 1.9.2.. Primary kinetic salt effect
- 1.9.3.. IUPAC recommendations for the representation of reaction mechanisms
- 1.9.4.. Nomenclature of coordination compounds
- 1.10.. Direct observation of the activated complex
- 1.10.1. Spectroscopy in the transition state region
- 1.11.. The influence of the solvent on the reaction rates and mechanisms
- 1.11.1.. Influence of solvent polarity on the rates of chemical reactions
- 1.12.. Steady-state approximation and its application to replacement reactions
- 1.13.. Reactions of ion pairs
- 1.14.. Primary and secondary kinetic isotope effects
- 1.14.1.. Primary kinetic isotope effects
- 1.14.2.. Secondary kinetic isotope effects
- 1.15.. Influence of tunneling on the primary and secondary kinetic isotope effects
- 1.15.1.. Extremely high kinetic isotope effects and tunneling
- 1.15.2.. Secondary [alpha]-deuterium kinetic isotope effect and tunneling
- References
- Bibliography
- 2.. Substitution reactions on metal complexes
- 2.1.. Introduction
- 2.2.. Reactions of organometallic complexes with halogenes (S[subscript E]2 mechanism)
- 2.3.. Labile and inert complexes
- 2.4.. Crystal-field theory
- 2.4.1.. Splitting of d orbitals in the octahedral crystal field
- 2.4.2.. Crystal-field stabilization energies of d orbitals for various geometric configurations, and substitution rates
- 2.4.3.. Influence of crystal field stabilization energies on the rates and mechanism of octahedral substitutions
- 2.5.. Ligand field and electron transitions
- 2.6.. Substitution reactions on octahedral complexes
- 2.6.1.. Rates of water exchange in octahedral aqua complexes
- 2.6.2.. Pressure dependence of the reaction rate constant; volume of activation
- 2.6.3.. Substitution of coordinated water of octahedral complexes with anions ("anations")
- 2.6.4.. Aquation and acid catalysis
- 2.6.5.. Base catalysis
- 2.6.6.. Stereochemistry of octahedral substitutions
- 2.6.7.. Attacks of reactants on ligands (not on metal)
- 2.6.8.. Linkage isomerism
- 2.7.. Nucleophilicity in inorganic chemistry
- 2.7.1.. n[subscript Pt] Scale
- 2.7.2.. The scale of Swain and Scott
- 2.7.3.. Edwards' scale
- 2.7.4.. The theory of "hard" and "soft" acids and bases
- 2.8.. Substitutions on square-planar complexes
- 2.8.1.. The mechanism of ligand replacements
- 2.8.2.. Trans effect
- 2.8.3.. Cis effect
- 2.8.4.. Leaving group effects
- 2.8.5.. Effect of the central metal ion
- 2.9.. Substitution reactions of tetrahedral complexes
- 2.10.. Substitutions of carbonyls
- 2.10.1.. Substitutions of the carbonyls of complexes with a metal-metal bond
- References
- Bibliography
- 3.. Oxidative additions and reductive eliminations
- 3.1.. Oxidative additions
- 3.1.1.. Two-electron oxidative additions
- 3.1.2.. One-electron oxidative additions
- 3.2.. Reductive eliminations
- References
- 4.. Molecular nonrigidity
- 4.1.. Pseudorotation
- 4.2.. Nonrigidity of metal carbonyls
- 4.3.. [(Fulvalene)tetracarbonyldiruthenium]. Storage of light energy
- References
- 5.. Electron-transfer reactions
- 5.1.. Introduction
- 5.2.. Franck-Condon principle
- 5.3.. Outer-sphere electron transfer
- 5.3.1.. Marcus theory of outer-sphere electron transfer
- 5.3.2.. Long-range electron transfers in biological systems
- 5.4.. Inner-sphere electron transfer
- 5.5.. Reactions with solvated electrons
- References
- Bibliography
- 6.. Reactions of free radicals
- 6.1.. Chain reactions
- 6.2.. Stability of the metal-carbon [sigma] bond
- 6.3.. Oxidation of transition metal complexes by hydroxyl radicals
- 6.4.. Reduction of transition metal complexes by organic radicals
- References
- 7.. Mechanism of vitamin B[subscript 12] action
- 7.1.. Introduction
- 7.2.. Mechanism of vitamin B[subscript 12] activity
- 7.3.. Difficulties in distinguishing D and I[subscript d] mechanisms
- References
- 8.. Kinetics and mechanisms of metalloporphyrin reactions
- 8.1.. Introduction
- 8.2.. Mechanism of metal incorporation into the porphyrin complex
- 8.3.. Metalloporphyrins as oxygen carriers
- 8.4.. Substitutions on metalloporphyrins
- 8.4.1.. Imidazole, an essential component of many biological systems; the nature of metal bonding
- 8.4.2.. Comparison of the bonding modes of imidazole and pyridine to a metal
- 8.5.. Nature of the bond of amine ligands to cobalt(III) in porphyrins; the relation of [sigma] to [pi] bonding
- 8.6.. Catalytic action of metalloporphyrins
- 8.7.. Why only porphyrins, but not their isomers, in nature
- 8.8.. Nitrosoamine complex of metalloporphyrin, a probable intermediate in the mechanism of nitrosoamine activation of cancer
- 8.9.. The sequence of bonded metalloporphyrins--a molecular photonic wire
- 8.10.. Metalloporphyrins, metallophthalocyanines and analogous complexes in photodynamic therapy of cancer
- 8.10.1.. Introduction
- 8.10.2.. Red light for photodynamic therapy: metallotexaphyrins of lutetium and gadolinium as photosensitizers in cancer therapy
- 8.11.. Some models of metalloenzymes
- References
- 9.. Metallocenes, strong electron donors
- 9.1.. Introduction
- 9.2.. Bonding in the [eta superscript 5]-(C[subscript 5]H[subscript 5])[subscript 2 Fe] complexes
- 9.3.. Stability of [alpha]-metallocenyl carbocations
- 9.4.. Secondary [alpha]-deuterium kinetic isotope effect and the structure of ferrocenylmethyl carbocation type transition state
- 9.4.1.. High secondary [alpha]-deuterium kinetic isotope effects for the primary carbon-oxygen cleavage in formolysis and acetolysis of dideuterioferrocenylmethyl benzoate
- 9.4.2.. Possible contribution of tunneling to the high secondary [alpha]-deuterium kinetic isotope effect
- 9.5.. Ferrocene ability to stabilize a carbenium ion
- 9.5.1.. Solvent variations and the rates of ferrocenylmethyl ester solvolyses
- 9.5.2.. Relative rates of ferrocenylmethyl benzoate solvolyses in formic and acetic acid
- 9.6.. Antitumor activity of metallocenes
- 9.7.. Ferrocenes as nucleophilic catalysts can mediate kinetic resolution
- 9.8.. Ferrocenes and molecular recognition
- 9.9.. Metal-metal interactions in linked metallocenes
- 9.9.1.. Metallocene derivatives
- 9.9.2.. Concluding remarks
- References
- 10.. Metal complexes in tumor therapy
- 10.1.. Introduction
- 10.1.1.. Chemotherapy of cancer
- 10.2.. Complexes of the cis-PtL[subscript 2]X[subscript 2] type as antitumor agents
- 10.3.. Second generation of cisplatin analogs
- 10.3.1.. The mechanism of antitumor activity of cisplatin
- 10.4.. Gold complexes as antitumor agents
- 10.5.. Antitumor activity of organogermanium compounds
- References
- 11.. Heterogeneous and homogeneous catalysis by metals and transition metal complexes
- 11.1.. Introduction
- 11.2.. Heterogeneous catalysis by metals and metal oxides
- 11.3.. Homogeneous catalysis by transition metal complexes
- 11.3.1.. Hydroformylation of unsaturated compounds
- 11.3.2.. Hydrocyanation of alkenes
- 11.3.3.. Polymerization of alkenes and alkynes; Ziegler-Natta catalysts
- References
- 12.. Chemical and biological nitrogen fixation
- 12.1.. Introduction
- 12.2.. Biological nitrogen fixation
- 12.2.1.. Nitrogen fixation in bacteria
- 12.3.. Reactions of N[subscript 2] with transition metal complexes
- References
- 13.. Cascade molecules (dendrimers)
- 13.1.. Introduction
- 13.2.. Methods of dendrimer preparation
- References
- 14.. Metal complexes with short memory effect
- 14.1.. Introduction
- 14.2.. Magnetic materials and information storage
- 14.3.. Hyperthermy treatment of some tumors
- References
- 15.. Some recent publications in the scientific spotlight
- 15.1.. Introduction
- 15.2.. C-Binding vs. N-binding of imidazoles to metal fragments
- References (section 15.2)
- 15.3.. Hexaphyrin, an expanded porphyrin ligand for the UO[subscript 2 superscript 2+] and NpO[subscript 2 superscript +] coordination
- References (section 15.3)
- 15.4.. Alkane picosecond carbon-hydrogen bond cleavage at the iridium carbonyl center
- References (section 15.4)
- 15.5.. Photochemical activation of the N[identical with]N bond in a dimolybdenum-dinitrogen complex
- References (section 15.5)
- 15.6.. Separation and purification of olefins using dithiolene complexes
- References (section 15.6)
- 15.7.. Highly efficient ring-opening metathesis polymerization (ROMP)
- References (section 15.7)
- 15.8.. Supramolecular cluster catalysis: benzene hydrogenation catalyzed by a cationic triruthenium cluster
- References (section 15.8)
- 15.9.. A trimer of zinc(II), ruthenium(II), and tin(IV) porphyrins called the trinity of metals
- References (section 15.9)
- 15.10.. Bis(1,2,3,4-[eta superscript 4]-anthracene)cobaltate(1-)
- References (section 15.10)
- 15.11.. sp-Carbon chains surrounded by sp[superscript 3]-carbon double helices: a class of molecules accessible by self-assembly and models for "insulated" molecular-scale devices
- References (section 15.11)
- 15.12.. Ferrocene and fullerene hybrid
- References (section 15.12)
- Epilogue
- Appendix
- Physical and chemical constants
- Conversion factors
- Some often used abbreviations
- Prefixes
- Electronic configurations of the elements
- Index
