1,1'-binaphthyl-based chiral materials : our journey /
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| Author / Creator: | Pu, Lin, 1965- |
|---|---|
| Imprint: | London : Imperial College Press ; Hackensack, NJ : Distributed by World Scientific Pub., c2010. |
| Description: | ix, 335 p. : ill. ; 24 cm. |
| Language: | English |
| Subject: | |
| Format: | Print Book |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/7892833 |
Table of Contents:
- Preface
- 1. Introduction About l,l'-Binaphthyls
- References
- 2. Main Chain Chiral-Conjugated Polymers
- 2.1. Introduction About Chiral-Conjugated Polymers
- 2.2. Binaphthyl-Based Polyarylenevinylenes
- 2.3. Binaphthyl-Based Polyarylenes
- 2.4. Binaphthyl-Based Polyaryleneethynylenes
- 2.5. Binaphthyl-Thiophene Copolymers
- 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers
- 2.7. Polybinaphthyls Without Conjugated Linkers
- 2.8. Propeller-Like Polybinaphthyls
- 2.9. Dipole-Oriented Propeller-Like Polymers
- 2.10. Binaphthyl-Based Polysalophens
- 2.11. Helical Ladder Polybinaphthyls
- References
- 3. Polybinaphthyls in Asymmetric Catalysis
- 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis
- 3.2. Synthesis of Major-Groove Poly (BINOL)s
- 3.3. Application of the Major-Groove Poly (BINOL)s to Catalyze the Mukaiyama Aldol Reaction
- 3.4. Application of the Major-Groove Poly (BINOL)s to Catalyze the Hetero-Diels-Alder Reaction
- 3.5. Using the Ti(IV) Complex of the Major-Groove Poly (BINOL) to Catalyze the Diethylzinc Addition to Aldehydes
- 3.6. Synthesis of the Minor-Groove Poly (BINOL)s
- 3.7. Application of the Major- and Minor-Groove Poly (BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes
- 3.8. Asymmetric Reduction of Prochiral Ketones Catalyzed by the Chiral BINOL Monomer and Polymer Catalysts
- 3.9. Asymmetric Epoxidation of ¿,ß-Unsaturated Ketones Catalyzed by the Minor- and Major-Groove Poly (BINOL)s
- 3.10. Asymmetric Diels-Alder Reaction Catalyzed by Poly (BINOL)-B (III) Complexes
- 3.11. 1,3-Dipolar Cycloaddition Catalyzed by the Minor- and Major-Groove Poly (BINOL)-A1(III) Complexes
- 3.12. Asymmetric Michael Addition Catalyzed by the Poly (BINOL)s
- 3.13. Synthesis and Study of Poly (BINAP)
- 3.14. Synthesis and Study of a BINOL-BINAP Copolymer
- References
- 4. Asymmetric Catalysis by BINOL and Its Non-polymeric Derivatives
- 4.1. Introduction
- 4.2. Asymmetric Alkyne Additions to Aldehydes
- 4.3. Asymmetric Arylzinc Addition to Aldehydes
- 4.4. Asymmetric Alkylzinc Addition to Aldehydes
- 4.5. Asymmetric TMSCN Addition to Aldehydes
- 4.6. Asymmetric Hetero-Diels-Alder Reaction
- References
- 5. Enantioselective Fluorescent Sensors Based on l,l'-Binaphthyl-Derived Dendrimers, Small Molecules and Macrocycles
- 5.1. Introduction
- 5.2. Using Phenyleneethynylene-BINOL Dendrimers for the Recognition of Amino Alcohols
- 5.3. Using Phenylene-BINOL Dendrimers for the Recognition of Chiral Amino Alcohols
- 5.4. Using Functionalized BINOLs for the Recognition of Amino Alcohols and Amines
- 5.5. Using Acyclic Bisbinaphthyls for the Recognition of ¿-Hydroxycarboxylic Acids and Amino Acid Derivatives
- 5.6. Using Diphenylethylenediamine-BINOL Macrocycles for the Recognition of ¿-Hydroxycarboxylic Acids
- 5.7. Using Cyclohexanediamine-BINOL Macrocycles and Their Derivatives for the Recognition of ¿-Hydroxycarboxylic Acids and Amino Acid Derivatives
- 5.8. Application of the Cyclohexanediamine-BINOL Macrocycle Sensor in Catalyst Screening 31
- 5.9. Using Monobinaphthyl Compounds for the Recognition of ¿-Hydroxycarboxylic Acids and Amino Acid Derivatives
- 5.10. Enantioselective Precipitation and Solid-State Fluorescence Enhancement in the Recognition of ¿-Hydroxycarboxylic Acids by Using Monobinaphthyl Compounds
- References
- 6. Miscellaneous Studies on Materials Related to l,l'-Binaphthyls
- 6.1. Chiral Molecular Wires
- 6.2. A Biphenol Polymer
- 6.3. Supramolecular Chemistry of Self-Assembly of Racemic and Optically Active Propargylic Alcohols
- References
- Index
