NMR studies of translational motion /

NMR studies of translational motion /

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Bibliographic Details
Author / Creator:Price, William S., 1964-
Imprint:Cambridge ; New York : Cambridge University Press, 2009.
Description:xxii, 393 p. : ill. ; 26 cm.
Language:English
Series:Cambridge molecular science
Cambridge molecular science series.
Subject:
Translational motion -- Measurement.
Reactivity (Chemistry)
Nuclear magnetic resonance.
Diffusion magnetic resonance imaging.
Diffusion magnetic resonance imaging.
Nuclear magnetic resonance.
Reactivity (Chemistry)
Format: E-Resource Book
URL for this record:http://pi.lib.uchicago.edu/1001/cat/bib/8209699
Hidden Bibliographic Details
ISBN:9780521806961
0521806968
Notes:Includes bibliographical references and index.
Electronic reproduction. Palo Alto, Calif. : ebrary, 2010. Available via World Wide Web. Access may be limited to ebrary affiliated libraries.
Table of Contents:
  • Preface
  • Acknowledgements
  • Abbreviations
  • 1. Diffusion and its measurement
  • 1.1. Introduction
  • 1.2. Types of translational motion-physical interpretation and significance
  • 1.3. Mathematical modelling of self-diffusion
  • 1.4. Propagation
  • 1.5. Solving the diffusion equation
  • 1.6. Mean square displacement, time-dependent diffusion coefficients and the diffusion ellipsoid
  • 1.7. Measurement timescales and restricted diffusion
  • 1.8. Diffusion in heterogeneous, porous and polymer systems
  • 1.9. Flow in porous media
  • 1.10. Techniques for measuring diffusion
  • References
  • 2. Theory of NMR diffusion and flow measurements
  • 2.1. Introduction
  • 2.2. Nuclear spins, magnetic gradients and motion
  • 2.3. Correlating the PGSE signal attenuation with diffusion
  • 2.4. Oscillating gradients, higher-order gradient pulse trains and probing D w (w)
  • 2.5. PGSE of freely diffusing multicomponent systems
  • 2.6. The long-range dipolar field and multiple echoes
  • References
  • 3. PGSE measurements in simple porous systems
  • 3.1. Introduction
  • 3.2. Experimental determination of &Pbar;(R, ¿)
  • 3.3. Experimental determination of the moments of &Pbar;(R, ¿)
  • 3.4. The spectral function and the return to origin probability
  • 3.5. Diffusive diffraction
  • 3.6. An example - diffusion between planes
  • 3.7. Diffusion in reflecting spheres
  • 3.8. Size distributions of the restricting geometry
  • 3.9. Finite gradient pulses and the validity of the SGP and GPD approximations
  • 3.10. Other methods for determining E(q, ¿)
  • References
  • 4. PGSE measurements in complex and exchanging systems
  • 4.1. Introduction
  • 4.2. Simple binding and exchange: the ärger equations
  • 4.3. Exchange between free and restricted sites
  • 4.4. Anisotropic and low dimensional diffusion
  • 4.5. General porous media
  • 4.6. Polymer diffusion
  • 4.7. Flow and velocity distributions
  • 4.8. Internal magnetic field gradients
  • References
  • 5. PGSE hardware
  • 5.1. Introduction
  • 5.2. Gradient coils and fringe fields
  • 5.3. Current amplifiers
  • 5.4. Connecting to the spectrometer
  • 5.5. Field-frequency locking
  • 5.6. Temperature control and calibration
  • References
  • 6. Setup and analysis of PGSE experiments
  • 6.1. Introduction
  • 6.2. Selection of PGSE parameters
  • 6.3. Sample preparation
  • 6.4. Gradient calibration
  • 6.5. Analysis
  • References
  • 7. PGSE hardware and sample problems
  • 7.1. Introduction
  • 7.2. RF problems
  • 7.3. Radiation damping and long-range dipolar field effects
  • 7.4. Convection and flow compensation
  • 7.5. Gradient constancy
  • 7.6. Background gradients
  • 7.7. Eddy currents and perturbation of B 0
  • 7.8. Gradient mismatch and sample movement
  • 7.9. Cross relaxation
  • 7.10. Homonuclear scalar couplings
  • References
  • 8. Specialised PGSE and related techniques
  • 8.1. Introduction
  • 8.2. Steady gradient and stray field measurements
  • 8.3. Multiple quantum and heteronuclear
  • 8.4. Fast sequences
  • 8.5. Distributions of relaxation times
  • 8.6. Multi-dimensional mixture separation and diffusion editing
  • 8.7. Double PGSE and multi-dimensional correlations
  • 8.8. Flow measurements
  • 8.9. Electrophoretic NMR
  • 8.10. Multiple spin-echoes and miscellaneous
  • References
  • 9. NMR imaging studies of translational motion
  • 9.1. Introduction
  • 9.2. Imaging - basic concepts
  • 9.3. Combining PGSE measurements with imaging
  • 9.4. Imaging-based flow measurements
  • References
  • 10. B 1 gradient methods
  • 10.1. Introduction
  • 10.2. B 1 gradients
  • 10.3. B 1 gradient diffusion measurements
  • 10.4. Miscellaneous
  • References
  • 11. Applications
  • 11.1. Introduction and reviews
  • 11.2. Applications to high-resolution NMR
  • 11.3. Biological and pharmaceutical studies
  • 11.4. Chemical and material studies
  • 11.5. Spin-diffusion
  • 11.6. Imaging-based studies
  • References
  • Appendix
  • Index

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