Redox systems under nano-space control /
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Imprint: | Berlin ; New York : Springer, c2006. |
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Description: | 1 online resource (xviii, 295 p.) : ill. |
Language: | English |
Subject: | |
Format: | E-Resource Book |
URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/8877550 |
Table of Contents:
- Cover
- Contents
- Part I: Redox Systems via d, p-Conjugation
- 1 Conjugated Complexes with Quinonediimine Derivatives
- 1.1 Introduction
- 1.2 Architecturally Controlled Formation of Conjugated Complexes with 1,4-Benzoquinonediimines
- 1.3 Redox-Switching Properties of Conjugated Complexes with 1,4-Benzoquinonediimines
- 1.4 Conclusion
- 1.5 References
- 2 Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathways
- 2.1 Dimensionality inMolecular-Wire Sensors
- 2.2 Analyte-Triggered Barrier Creation in Conducting Polymers
- 2.3 Isolated Nanoscopic Pathways
- 2.4 Langmuir-Blodgett Approaches to Nanofibrils
- 2.5 Molecular Scaffolds for the Isolation of Molecular Wires
- 2.6 Summary and Future Prospects
- 2.7 References
- 3 Metal-Containing p-Conjugated Materials
- 3.1 Introduction
- 3.2 Metal-Complex-Containing Conjugated Materials
- 3.3 Metal-Nanoparticle-Containing Conjugated Materials
- 3.4 Applications
- 3.5 Conclusions
- 3.6 References
- 4 Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models forMolecular Wires
- 4.1 Introduction
- 4.2 Ruthenium Allenylidene and Acetylide Building Blocks: Basic Properties
- 4.3 Bimetallic Complexes from the Ru(dppe)[sub(2)] System.
- 4.4 Connection of Two Carbon-Rich Chains with the Ruthenium System
- 4.5 Trimetallic and Oligomeric Metal Complexes with Carbon-Rich Bridges
- 4.6 Star Organometallic-Containing Multiple Identical Metal Sites
- 4.7 Conclusion
- 4.8 References
- 5 Molecular Metal Wires Built from a Linear Metal Atom Chain Supported by Oligopyridylamido Ligands
- 5.1 Introduction
- 5.2 Synthesis of Oligopyridylamine Ligands
- 5.3 Dimerization by Self-Complementary Hydrogen Bonding
- 5.4 Complexation of Oligopyridylamine Ligands
- 5.5 Mono- and Dinuculear Complexes
- 5.6 Structures of Linear Multinuclear Nickel Complexes
- 5.7 Structures of Linear Multinuclear Cobalt Complexes
- 5.8 Structures of Linear Multinuclear Chromium Complexes
- 5.9 Structures of Triruthenium and Trirhodium Complexes
- 5.10 Complexes of Modified Ligands
- 5.11 Electrochemical Properties of the Complexes
- 5.12 Scanning Tunneling Microscopy Studies
- 5.13 Summary
- 5.14 References
- 6 Multielectron Redox Catalysts in Metal-Assembled Macromolecular Systems
- 6.1 Introduction
- 6.2 Multielectron Redox Systems
- 6.3 Multinuclear Complexes as Redox Catalysts
- 6.4 Macromolecule-Metal Complexes
- 6.5 Metal Ion Assembly on Dendritic Macromolecules
- 6.6 Conclusion
- 6.7 References
- Part II: Redox Systems via Coordination Control
- 7 Triruthenium Cluster Oligomers that Show Multistep/Multielectron Redox Behavior
- 7.1 Introduction
- 7.2 Syntheses of Oligomers 1 and 2
- 7.3 Redox Behavior of 1 and 2
- 7.4 Conclusion
- 7.5 References
- 8 Molecular Architecture of Redox-Active Multilayered Metal.