Construction and reactivity of Pt-based bi-component catalytic systems /

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Bibliographic Details
Author / Creator:Mu, Rentao, author.
Imprint:Berlin, Germany : Springer, [2017]
Description:1 online resource : illustrations
Language:English
Series:Springer theses
Springer theses.
Subject:
Format: E-Resource Book
URL for this record:http://pi.lib.uchicago.edu/1001/cat/bib/11307900
Hidden Bibliographic Details
ISBN:9783662552445
3662552442
9783662552421
3662552426
Digital file characteristics:text file PDF
Notes:"Doctoral Thesis accepted by Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China."
Includes bibliographical references and index.
Online resource; title from PDF title page (EBSCO, viewed June 27, 2017).
Summary:In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the "sandwich-like" structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene.
Other form:Print version: Mu, Rentao. Construction and reactivity of Pt-based bi-component catalytic systems. Berlin, Germany : Springer, [2017] 9783662552421 3662552426
Standard no.:10.1007/978-3-662-55244-5